Synthesis of porous aromatic framework with tuning porosity via ionothermal reaction.
نویسندگان
چکیده
PAF-16 which is based on tetrahedral units (TCPSi) and triangular building units, shows both high thermal stability and high chemical stability. The surface area of PAF-16 can be tuned by changing the reaction temperature and ratio of monomer and catalyst. PAF-16 also shows considerable adsorption capacity of CO(2).
منابع مشابه
Synthesis of Different Copper Oxide Nano-Structures From Direct Thermal Decomposition of Porous Copper(ΙΙ) Metal-Organic Framework Precursors
Copper oxide nanostructures have been successfully synthesized via one-step solid-state thermolysis of two metal-organic frameworks, [Cu3(btc)2] (1) and [Cu(tpa).(dmf)] (2), (btc = benzene-1,3,5-tricarboxylate, tpa = therephtalic acid = 1,4-benzendicarboxylic acid and dmf = dimethyl formamide) under air atmosphere at 400, 500, and 600°C. It has also been found that the reaction temperature pla...
متن کاملTarget synthesis of a novel porous aromatic framework and its highly selective separation of CO(2)/CH(4).
A novel porous aromatic framework based on tetra-(4-anilyl)-methane and cyanuric chloride has been designed and synthesized successfully, which possesses permanent porosity and high selectivity of CO2 towards CH4.
متن کاملA functional triazine framework based on N-heterocyclic building blocks
Covalent organic frameworks constitute a subclass of polymeric materials offering enhanced porosity, functionality and stability. In this work a covalent triazine framework based on bipyridine building blocks is presented, along with a comprehensive elucidation of its local structure, porosity, and capacity for metal uptake. A typical synthesis was carried out under ionothermal conditions at 40...
متن کاملThe ionothermal synthesis of SIZ-6--a layered aluminophosphate.
A new layered open framework aluminophosphate has been prepared by ionothermal synthesis using an ionic liquid as the reaction solvent and structure-directing agent.
متن کاملMechanical Synthesis of Zn-HKUST-1 Metal-Organic Framework and Investigation its Fluorescence Sensing Ability Toward to Detect Explosive-like Nitro aromatic Analytes Such as TNT
Metal-Organic Framework (MOFs) are new crystalline materials which because of having propertiessuch as high porosity, optical and electrical properties, etc., have been considered in areas such as gasstorage, catalysis, pollutants removal and so on. Therefore, in order to develop these compounds andtheir use in this study, in this work, Zn-HKUST-1 metal-organic framework was synthesized by fast...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Dalton transactions
دوره 41 14 شماره
صفحات -
تاریخ انتشار 2012